Volume 307
Main Index

Issue 1, Pages 1-137 (10 June 1986)

Formation of Fe3(NCMe)(CO)9 during the reaction of Fe3(μ3-CMe)(CO)10X clusters with alkynes (X = no) or diazoalkanes (X = H). First examples of ethylidyne-nitrogen coupling to acetonitrile Pages C5-C6 Didier Nuel, René Mathieu

Oxidative addition reactions of Cp*Os(CO)(PMe2Ph)Me (Cp* = η5-C5Me5). Isolation of intermediates during alkyl—metal electrophilic cleavage reactions Pages C1-C4 Laura J. Sanderson, Michael C. Baird

Author index Page C12

Organomercury compounds in organic synthesis : by R.C. larock (Reactivity and Structure: concepts in organic chemistry, vol. 22), springer verlag, 1985 xi + 423 pages, DM 268, ISBN 3-540-13749-1. Pages C10-C11 Penny A. Chaloner

Synthesis and crystal structure of μ-chloro-μ-(diphenylethenyl)hexacarbonyldiiron(Fe---Fe) Pages C7-C9 Josep Ros, Josep M. Viñas, René Mathieu, Xavier Solans and, Mercè Font-Bardia

Announcement Page C11

New bicyclic organylboronic esters derived from iminodiacetic acids Pages 1-6 Teresa Mancilla, Rosalinda Contreras, Bernd Wrackmeyer

New precursors to silafluorenes Pages 7-14 Joyce Y. Corey, Lihsueh S. Chang

Origine de l'étain formé durant les électrolyses dudichlorure de méthyphénylétain Pages 15-22 Michéle Engel, Marguerite Devaud

The first cationic indenyl-f-metal complexes with pentagonal bipyramidal geometry. Crystal structures of [C9H7UBr2(CH3CN)4]+2 [UBr6]2− and [{C9H7UBr(CH3CN)4}2O]2+ [UBr62− Pages 23-37 W. Beeckman, J. Goffart, J. Rebizant, M. R. Spirlet

Mononuclear carbonyl manganese(I) and molybdenym(II) complexes with chelating biimidazole, bibenzimidazole or tetramethylbiimidazole ligands Pages 39-47 M. P. Gamasa, E. Garcia, J. Gimeno, C. Ballesteros

Aromaten(phosphan)metall-komplexe : XI. Fünfgliedrige osma-heterocyclen durch alkin-insertion in eine Os---I- oder Os-H-bindung Pages 49-59 H. Werner, R. Weinand, H. Otto

Synthetic studies of the reaction between aldehydes and the triosmium cluster [Os3(CO)10(NCMe)2] Pages 61-64 Brian F. G. Johnson, Jack Lewis, Timothy I. Odiaka

Synthesis and catalysis of a silica-supported cobalt carbonyl cluster Pages 65-70 Yun-Pu Wang, Shu-Mei Zhang, Ai-Min Zhang, Nan Wu, Yu-Zhong Luo and, Hong-Xiang Fu

Reactivity patterns in the reactions of [Rh(CO)2Cl]2 with chelating ketones Pages 71-82 J. William Suggs, Michael J. Wovkulich, Paul G. Williard, Ken S. Lee

Tetrafluorobenzobarreleneiridium complexes with 1,10- phenanthroline,2,2′-bipyridine and diketonate ligands. Crystal structure of [IrI2(TFB)(phen)]ClO4·(CH32CO (TFB = 5,6,7,8- tetrafluoro-1,4-dihydro-1,4-ethenonapthalene, PHEN = 1,10- phenanthroline) Pages 83-92 L. A. Oro, D. Carmona, M. A. Esturuelas, C. Foces-Foces and, F. H. Cano

1η-komplexierung eines 1-phosphaallens mit nickeltetracarbonyl Pages 93-95 R. Appel, F. Knoch, V. Winkhaus

The reactions of (η5-C5H5)NiO(s)3(μ-H)3(CO)9 with group V donor ligands. Spectroscopic characterization of the disubstituted derivatives, and crystal structure of (η5-C5H5)NiO(s)3(μ-H)3(CO)7(PMe2Ph)2 Pages 97-105 Enrico Sappa, Maria Luisa Nanni Marchino, Giovanni Predieri, Antonio Tiripicchio and, Marisa Tiripicchio Camellini

Palladium(II) and platinum(II) derivatives with chiral 2,2′-bipyridines. X-ray structure of C18H15ClN2Pd; C- and N-intramolecular coordination in a six-membered metallacycle Pages 107-114 Giovanni Minghetti, Maria A. Cinellu, Giorgio Chelucci, Serafino Gladiali, Francesco Demartin and, Mario Manassero

Mononuclear platinum(II) chloride complexes with N-[(triorganylsilyl)alkyl]ethylenediamines Pages 115-119 Chunye Hu, Ji-Gang He, D. H. O'Brien and, Kurt J. Irgolic

31P-UND195Pt-NMR-Untersuchugen an substituierten cis-und trans-Bis(Phenyl)Bis(Tri-n-Butylphosphan)-platin(II)-verbindungen Pages 121-127 Helmuth G. Alt, Wolf-Dieter Müller, J. Unsin, Hans Albert Brune

Synthesen nitro-substituierter cis-bis(phenyl)platin(II)-verbindungen Pages 129-137 Hans Albert Brune, Bernhard Stapp, Günther Schmidtberg

Issue 2, Pages 139-272 (17 June 1986)

The synthesis of a novel trimetallic complex containing three redox centres and an assessment of inductive effect transmission through an iron atom Pages C19-C22 Paul D. Beer, Stephen M. Charsley, Christopher J. Jones, Jon A. McCleverty

Isolation and reactions of 6-H3N-6-CB9H11 Pages C13-C15 T. Jelinek, B. Pleek, S. Hemánek

Cobalt atoms as catalysts of the synthesis of pyridines from nitriles and acetylenes Pages C35-C37 Giovanni Vitulli, Sergio Bertozzi, Raffaello Lazzaroni, Piero Salvadori

C---C-Verknüpfund von alkenen mit CO2 an nickel(O); herstellung von zimtsäure aus styrol Pages C38-C40 Heinz Hoberg, Yolande Peres, Armin Milchereit

Die ersten komplexen derivate des 1,3-diborabenzols: Zwei [n6-1,3-bis(diisopropylamino)-1,3-dibora-5-cyclohexen-2,4-diyl]eisen-komplexe Pages C16-C18 G. E. Herberich, H. Ohst

Author index Page C48

C---C-Verknüpfung von alkenen mit CO2 an nickel(O); n-pentesäuren aus ethen Pages C41-C43 Heinz Hoberg, Yolande Peres, Armin Milchereit

Photochemistry of M(η5-C5H5)2(H)CO and M(η5-C5H5)2H3 (M = Nb, Ta) in low-temperature matrices Page C47

Six-membered cyclometallated compounds of methylbenzalazines with Pd---C(aliphatic)bonds Pages C44-C46 R. M. Ceder, J. Granell, J. Sales

From an {Fe4S4}-cluster to {Fe2S2}- and {Fe3S}-carbonyls. Crystal structure of [Fe3S(CO)9]2− Pages C31-C34 Faris T. Al-Ani, David L. Hughes, Christopher J. Pickett

Bifunctionalization of hexamethylbenzene via temporary coordination to Fe2+ Pages C27-C30 Dominique Mandon, Didier Astruc

Addition of methylene groups to the unsaturated complex [FeW(μ-CC6H4Me-4)(CO)5(η-C5Me5)]: μ-alkenyl ligand rearrangements at a dimetal centre Pages C23-C26 Esther Delgado, Joachim Hein, John C. Jeffery, Andrew L. Ratermann, F. Gordon A. Stone

Dissymetrisation de la molecule de glyoxal : II. Action des organometalliques sur l'acetoxy-1 triethoxy-1,2,2 ethane Pages 139-144 A. Stambouli, R. Amouroux, F. Chastrette, M. Chastrette, G. Mattioda and, A. Blanc

On the stoicheiometry of aluminium alkyl-ester complexes Pages 145-149 Giovanni Fochi

Flow pyrolysis of hexafluorodisilane as a source of highly reactive difluorosilylene Pages 151-155 Stanislaw Konieczny, Peter P. Garspar, Joda Wormhoudt

Organoborierung von alkinylstannanen : XVI. borol-synthese über die organoborierung von BIS(alknyl)Boranen Pages 157-165 Angelika Sebald, Bernd Wrackmeyer

Estimation of stepwise M-L bond dissociation enthalpies in M(η-C5H5)2L2 complexes Pages 167-176 Maria J. Calhorda, Alberto R. Dias, Adelino M. Galvão, José A. Martinho Simões

The reaction of TiCl4 and CpTiCl3 with tridentate triaminosilyl ligands. crystal and molecular structure of a titanibicycloheptane with an unusual Si-N-Li-Cl-Ti chain Pages 177-190 D. J. Brauer, H. Bürger, G. R. Liewald

Dielectric, electro-optic and infrared and 1H NMR spectral properties of methyl- and t-butyl-substituted (η6-benzene)tricarbonylchromium(0) complexes: a study of solvent effects Pages 191-203 M. J. Aroney, M. K. Cooper, R. K. Pierens, S. J. Pratten, S. W. Filipczuk

Interactions des complexes du chrome ou du tungstene a ligande germylene avec des dipoles 1,3 (nitrones, oxaziridines) Pages 205-218 A. Castel, P. Rivière, J. Satgé, M. Ahbala, J. Jaud

Synthesis and ligand substituion chemistry of dinuclear, phosphido-bridged complexes of manganese. X-ray crystal structures of Mn2(μ-H)(μ-Cy2P)(CO)7(PCy2H)(1) and Mn2(μ-H)(μ-Cy2P)(CO)6(PMe32 Pages 219-229 Atta M. Arif, Richard A. Jones, Stuart T. Schwab

Preparation, structure and reactivity of (η6-1-triphenylstannylbenzene)(η5-cyclopentadienyl)iron(II) hexafluorophosphate Pages 231-236 C. S. Frampton, K. G. Ofori-Okai, R. M. G. Roberts, J. Silver

Reversible alkin-addition an rp-verbrückte carbonyleisen-cluster Pages 237-253 Konrad Knoll, Gottfried Huttner, Laszlo Zsolnai

Synthesis of cationic indenyliron complexes: [η5-C9H7Fe(CO)2L]+ (L = phosphine, phosphite, CO) Pages 255-261 Hassan H. Hammud, Grainne M. Moran

Reductive carbonylation of carboxylic esters in the presence of homogeneous ruthenium-cobalt systems. Homologation of the alkoxy moiety Pages 263-272 Gérard Jenner, Philippe Andrianary

Issue 3, Pages 273-398 (24 July 1986)

Gmelin handbook of inorganic chemistry. 8th edition. Cu. Organocopper compounds part 1. : By J. Faust, J. Füssel, and H. Somer. Springer-Verlag Berlin etc., 1985, x + 470 pages. DM 1725. ISBN 3-540-93517-7. Page C63 Colin Eaborn

The generality of metal atom-free radical reactions and synthesis of new trifluoromethylalkyls of gold(III) and silver Pages C58-C62 M. A. Guerra, T. R. Bierschenk, R. J. Lagow

Subject index Pages C66-C71

Author index Pages C64-C65

Transition metal promoted reactions : XIV. Novel reductive coupling of thioketals with molybdenum hexacarbonyl Pages C49-C51 Chi Sang Wong, Wing Sang Leung, Lam Lung Yeung, Tien-Yau Luh

The insertion of cycloheptatriene and cyclohepta-1,3-diene into the Ru---H bond of RuHCl(PPh3)3 to give Ru(η5-C7H9)Cl(PPh3)2 and Ru(η3-C7H11)Cl(PPh3)2 Pages C55-C57 Maria Grassi, Brian E. Mann, Paul Manning, Catrion M. Spencer

Thermally induced elimination of stilbene from (η5-C5H5)2Zr[CH(SC6H5)C6H5]2 Pages C52-C54 Eric A. Mintz, A. Steven Ward

Ultrasonic irradiation in the synthesis of trimethylaluminum from methyl iodide via methylaluminum sesquiiodide Pages 273-278 Paw-Hwa Yang, Kou-Fu Liou, Yih-Tsung Lin

Siliciumorganische verbindungen : LXXXIV. Silylierte cyclobutene Pages 279-284 Leonhard Birkofer, Dietmar Eichstädt

Reaction of allylic arsenites with low valent transition metal complexes Pages 285-289 Xiyan Lu, Ling Lu

Alkenylphosphane RPX2 und R2PX (X = NEt2, CI): IHRE funktion als einzähnige liganden und potentiell hemilabile chelatbildner in metall(0)-komplexen Pages 291-305 Klaus Diemert, Beatrix Kottwitz, Wilhelm Kuchen

He(I) and He(II) photoelectron spectra of some mixed sandwich compounds of titanium, zirconium and hafnium Pages 307-317 R. R. Andréa, A. Terpstra, A. Oskam, P. Bruin and, J. H. Teuben

Mono(η5-cyclopentadienyl)-titan(IV)- und -zirconium(IV)-komplexe mit einem oder zwei toluol-3,4-dithiolat-liganden Pages 319-325 H. Köpf, T. Klapötke

Perfluoromethyl-element-liganden : XXXVI. Chrom-, molybdän- und wolframkomplexe des typs M(CO)5L und M(CO)4L2 mit mercaptophosphan-liganden Pages 327-341 J. Grobe, D. Le Van, W. Meyring

Cluster chemistry : XXXXIV. X-ray structures of [Ru3(CO)11(CNBut)] (at 130 K) and [Os3(CO)11(CNBut)] (at 295 K) Pages 343-350 Michael I. Bruce, Geoff N. Pain, Caroline A. Hughes, Jennifer M. Patrick, Brian W. Skelton and, Allan H. White

Mixed (η2:η4)-coordination of para-semiquinoid triene ligands (1-methylene-4,4-dialkyl-2,5-cyclohexadienes) with two transition metal centres in bi- and tri-nuclear rhodium(I) complexes Pages 351-362 V. A. Nikanorov, V. I. Rozenberg, V. I. Bakhmutov, O. A. Reutov, B. I. Ginzburg, V. V. Kaverin and, V. P. Yur'ev

π-cyclohexadienone derivatives of rhodium(I) acetylacetonate. Crystal and molecular structure of rhodium (η4-4-methyl-4-exo-trichloromethyl-2,5-cyclohexadiene-1-one)(pentane-O,O′-2,4-dionate) Pages 363-376 V. A. Nikanorov, V. I. Rozenberg, A. I. Yanovsky, Yu. T. Struchkov, O. A. Reutov, B. I. Ginzburg, V. V. Kaverin and, V. P. Yur'ev

trans-chloro(N,N-dimethyl--phenylglycine)-(3-methyl-1-phenylpent-1-ene)platinum(II) complexes. HPLC separation and identification of all the diastereomers Pages 377-383 Dietmar Schmidt, Emanuel Gil-av

Gold clusters: synthesis and characterization of [Au8(PPh3)7(CNR)]2+, [Au9(PPh36(CNR2]3+ and [Au11(PPH37(CNR)2O]2+ and their reactivity towards amines. The crystal structure of [Au11(PPh3)7(CN-i-Pr)2I](PF6)2 Pages 385-398 W. Bos, R. P. F. Kanters, C. J. Van Halen, W. P. Bosman, H. Behm, J. M. M. Smits, Paul T. Beurskens, J. J. Bour, L. H. Pignolet